热修饰的纳米晶牛吸收剂用于甲基蓝色封存:平衡,动力,热力学,人工智能和DFT研究
Abisoye Abidemi Adaramaja1, Abayomi Bamisaye1, Shakirudeen Modupe Abati1
1Department of Chemistry, Faculty of Natural and Applied Sciences, Lead City University Ibadan Oyo State Nigeria abayomibamisaye@gmail.com.
RSC advances
|April 22, 2024
概括
热修饰的纳米晶牛 (TMNSS) 有效地从废水中去除甲蓝 (MB) 染料. 这种可持续的生物吸收剂显示出高效率和工业废水处理的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 纳米技术纳米技术
背景情况:
- 工业废水往往含有危险的染料,如甲蓝 (MB).
- 开发可持续和高效的吸附剂对于去除染料至关重要.
- 牛是一个未充分利用的,潜在的有价值的生物吸收材料.
研究的目的:
- 研究热修饰的纳米晶牛 (TMNSS) 作为MB染料去除的新生物吸收剂.
- 为了优化吸附参数和特征TMNSS材料.
- 通过同热,动力和热力学模型,与ANFIS和DFT一起分析吸附机制.
主要方法:
- 进行了批量吸附实验,对接触时间,温度,pH值,吸附剂剂量和初始MB度进行了变化.
- 使用SEM,EDS,XRD和FTIR进行吸附剂表征.
- 使用弗洛伊德利希等热量,伪二次动力学,ANFIS和DFT进行吸附过程分析.
主要成果:
- 在最佳条件下 (pH3.0,10毫克剂量,30°C) TMNSS显示出高的MB去除效率 (96.48%).
- 吸附遵循弗洛伊德利希等热量和伪二次动力学,表明化学吸附和多层吸附.
- ANFIS和DFT的分析证实了实验发现,并提供了对MB-吸收剂相互作用的见解.
结论:
- 热修饰的纳米晶牛是一种有希望的,可持续的生物吸收剂,用于去除甲蓝色染料.
- 吸附过程是外热的,自发的,由化学吸附驱动.
- TMNSS为染料污染的工业废水处理提供了有效的解决方案.
相关概念视频
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