新型相变材料的热性能基于含有乙醇胺和酸的蛋白离子液体,用于高效的热能存储
Masumeh Mokhtarpour1, Ali Rostami2, Hemayat Shekaari1
1Department of Physical Chemistry, University of Tabriz, Tabriz, Iran.
Physical chemistry chemical physics : PCCP
|April 24, 2024
概括
新的离子液态相变材料 (PCM) 提供环保的热能存储. 这些新型材料在两个多小时内表现出稳定的能量转换,为先进的能量收集应用铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 收集能源 收集能源
- 热化学 热化学 热化学
背景情况:
- 换相材料 (PCM) 对于提高热能存储 (TES) 性能至关重要.
- 离子液体 (ILs) 由于其调节性特性,为TES应用提供了一个有前途的材料类.
- 开发具有成本效益,安全和环保的PCM对于能源采集的广泛采用至关重要.
研究的目的:
- 首次将新型离子液体,特别是2-乙酸 ([HEA]Ste),2-乙酸 ([DHEA]Ste) 和2-乙酸 ([THEA]Ste) 作为相变材料 (PCM) 引入市场.
- 研究这些合成的基于IL的PCM的热特性,化学成分,微观结构和热稳定性.
- 评估这些IL-PCM在热电发生器 (TEG) 系统中的潜力,用于实际的能源采集应用.
主要方法:
- 化学组成和微观结构的表征使用福里埃变换红外光谱 (FT-IR) 和扫描电子显微镜 (SEM).
- 通过差分扫描热量计 (DSC) 评估热性质,包括潜在的聚变热和特定热容量.
- 使用热重力测量分析 (TGA) 和使用原子力显微镜 (AFM) 的纳米尺度表面分析来评估热稳定性.
- 定制能源采集装置的制造和测试,将IL-PCM与商用热电发电机 (TEG) 集成在一起.
主要成果:
- 合成的ILs ([HEA]Ste,[DHEA]Ste,[THEA]Ste) 在30-100°C范围内表现出显著的潜在聚变热量 (分别为171.12,152.58,136.55kJ-1kg)
- [HEA]Ste表现出卓越的热稳定性,保持99.5%的完整性.
- 开发的TEG系统成功地将热能转化为电能,在热源被移除后,在2个多小时内提供持续的输出电压.
结论:
- 研究的离子液体是热能储存和采集的有效和有前途的相变材料.
- 这些基于IL的PCM为TES应用提供了安全,成本效益和环保的替代方案.
- 从TEG系统中证明的长期电能输出突出了这些新材料在可持续能源解决方案中的实际潜力.
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