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Updated: Jun 28, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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精确调节用于光催化的一维共价有机框架的链边结构微环境中的光催化

Hongjie Yang1, Jinfeng Wang1, Rui Zhao2

  • 1Department of Materials-Oriented Chemical Engineering, School of Chemical Engineering, Fuzhou University, Fuzhou, 350116, P. R. China.

Small (Weinheim an der Bergstrasse, Germany)
|April 25, 2024
PubMed
概括

设计具有全碳链边缘的1D共价有机框架 (COF) 通过增强电子传输来优化光催化. 这提高了光诱导电子转移-原子转移基聚合反应 (PET-ATRP) 的性能.

关键词:
1D 1D 1D 1D 1D 1D 1D 1D 1D原子转移激素聚合的聚合方式协价有机框架 协价有机框架氧气 氧气 氧气 氧气光催化作用的光催化作用

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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