用于甲同位素分析的腔环减光谱仪,使用1.65微米分布式反二极管激光器与光纤反循环
Ryohei Terabayashi1, Fumiko Yoshida2, Takanori Kunimaru2
1Nuclear Professional School, The University of Tokyo, 2-22, Shirakata-Shirane, Tokai, Ibaraki 319-1118, Japan.
The Review of scientific instruments
|April 25, 2024
概括
一个新的甲光谱仪使用光学反实现了甲同位素 (12CH4和13CH4) 的ppt级检测极限. 该仪器准确地测量了空气样本中的环境甲度和同位素比率.
科学领域:
- 大气科学 大气科学
- 分析化学 分析化学
- 频谱学是一种光谱学.
背景情况:
- 甲 (CH4) 是一种强有力的温室气体,同位素分析 (12CH4和13CH4) 对于来源分配至关重要.
- 高精度甲同位素分析需要敏感和稳定的仪器仪表.
研究的目的:
- 为精确的甲同位素分析开发了一种1.65微米腔圈式甲光谱仪.
- 提高仪器灵敏度和环境空气测量检测极限.
主要方法:
- 实现光学反与外部光纤腔和反射器,以减少激光线宽和提高灵敏度.
- 使用腔环下降光谱 (CRDS) 进行高分辨率吸收测量.
- 在100 Torr气压下使用艾伦-韦尔图和基线噪声分析评估检测极限.
主要成果:
- 对于12CH4和13CH4度,在每万亿分之一 (ppt) 的水平上达到检测极限.
- 从基线噪声估计时,观察到的剩余周期性背景振荡限制了检测到每十亿分之一 (ppb).
- 证明了大气空气中环境甲的直接测量,与参考值有很好的一致性.
结论:
- 开发的具有光学反的1.65微米CRDS光谱仪为甲同位素分析提供了高灵敏度.
- 该仪器能够实时直接测量环境中甲度和13CH4比率.
- 需要进一步改进,以克服剩余的背景振荡,以实现最佳的ppb级检测.
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