含有添加剂的双-CN组的电解质设计,使高压Na3V2 (PO4) 2F3的离子电池成为可能
Mingqin Jiang1,2, Tianyu Li1, Yanling Qiu1
1Division of Energy Storage, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
Journal of the American Chemical Society
|April 26, 2024
概括
研究人员开发了一种用于高能量密度离子电池的新电解质添加剂. 这种添加剂通过在阴极上形成保护界面来增强循环稳定性,从而提高电池性能.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 离子电池 (SIB) 对于储能至关重要,其 Na3V2 ((PO4) 2F3 阴极提供高能量密度.
- 高压SIB的运行需要电解质,在高达4.2V的电位与Na/Na+相对抗性.
- 提高高压SIB的循环性需要稳定的电极-电解质接口.
研究的目的:
- 为离子电池设计和合成一种高压电解质添加剂.
- 通过使用丁烯添加剂来研究接口形成的机制.
- 用开发的电解质评估SIB的电化学性能和循环稳定性.
主要方法:
- 电解质配方含有丁酸盐添加剂 (例如酸盐).
- 电化学特征包括循环电压测量和静电循环.
- 用于研究接口组成的表面分析技术 (例如XPS,EIS).
主要成果:
- 丁烯添加剂促进了Na3V2(PO4) 2F3阴极上形成一个稳定的绝缘接口层 (CN-/NCO-/Na3N丰富).
- 使用设计的电解质的SIB在高电压 (2-4.3V与Na/Na+) 中表现出极好的循环稳定性.
- 具体例子包括在1000个循环后在1°C时保持95.07%的容量 (1,5-迪亚诺) 和在5°C时保持93.0%的容量.
结论:
- 丁烯添加剂在构建高压离子电池的坚固固体电解质介面上是有效的.
- 拟议的电解质设计策略显著提高了基于Na3V2(PO4) 2F3的SIB的循环性和稳定性.
- 这项工作为开发下一代高能量密度电池的先进电解质提供了一种新的方法.
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