青铜耳环遗迹中的微观结构和离子腐蚀性能
Zhiqiang Song1,2, Ojiyed Tegus1,2
1Institute for the History of Science and Technology, Inner Mongolia Normal University, 81 Zhaowuda Road, Hohhot 010022, China.
Materials (Basel, Switzerland)
|April 27, 2024
概括
离子加速青铜腐蚀,在较高度下增加腐蚀速率. 来自内蒙古的铜耳环显示出经过加工的硬化结构,并在盐溶液中形成保护性氧化物层.
科学领域:
- 材料科学 材料科学 材料科学
- 考古金属术是一种考古金属术.
- 腐蚀科学 腐蚀科学
背景情况:
- 青铜文物容易受到环境退化的影响.
- 了解腐蚀机制对于文物保存至关重要.
研究的目的:
- 为了研究离子对青铜耳环腐蚀的影响.
- 分析考古铜的微观结构和腐蚀行为.
主要方法:
- 在X射线衍射 (XRD) 中.
- 光学显微镜 (OM) 的使用
- 扫描电子显微镜 (SEM) 的使用
- 电子反射衍射 (EBSD) 是一种电子反射衍射技术.
- 电化学测试 电化学测试 电化学测试
- 沉浸试验是一项沉浸试验.
主要成果:
- 在青铜表面上发现的工业硬化结构 (结合,等轴晶体).
- 腐蚀电流密度随着化物度的增加 (10-3到1mol/L NaCl).
- 一个金属氧化物被动化层,在3天浸泡在0.5%NaCl中后形成.
结论:
- 离子显著影响铜合金腐蚀.
- 较高的化物度加快了青铜的腐蚀速度.
- 腐蚀洞察力对于在化物丰富的环境中保存青铜文物至关重要.
更多相关视频
12:18Co-localizing Kelvin Probe Force Microscopy with Other Microscopies and Spectroscopies: Selected Applications in Corrosion Characterization of Alloys
Published on: June 27, 2022
2.6K
10:05Metal Corrosion and the Efficiency of Corrosion Inhibitors in Less Conductive Media
Published on: November 3, 2018
17.9K
相关概念视频
Corrosion of Reinforcement
178
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
178
Corrosion
24.1K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
24.1K
Electron Affinity
35.5K
The electron affinity (EA) is the energy change for adding an electron to a gaseous atom to form an anion (negative ion).
35.5K
Electrodeposition
630
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
630
Electrophilic Aromatic Substitution: Chlorination and Bromination of Benzene
8.0K
Chlorination and bromination are important classes of electrophilic aromatic substitutions, where benzene reacts with chlorine or bromine in the presence of a Lewis acid catalyst to give halogenated substitution products. A Lewis acid such as aluminium chloride or ferric chloride catalyzes the chlorination, and ferric bromide catalyzes the bromination reactions. During the bromination of alkenes, bromine polarizes and becomes electrophilic. However, in the bromination of benzene, the bromine...
8.0K
