构成比对聚氨粘土膨胀行为的影响
Xiaolong Li1,2, Cen Peng1,2, Yanna Ao1,2
1School of Water Conservancy and Transportation, Zhengzhou University, Zhengzhou 450001, China.
Materials (Basel, Switzerland)
|April 27, 2024
概括
具有受控膨胀率的聚氨合剂配方是精密空隙填充的关键. 泡剂度显著影响膨胀,指导特定应用的材料选择.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 聚合物化学 聚合物化学
背景情况:
- 发泡型聚氨粘合剂的受控扩张对于空隙填充而不会损坏周围结构至关重要.
- 了解材料组成对膨胀性能的影响对于优化合剂应用至关重要.
研究的目的:
- 研究不同成分对定制聚氨接合材料扩张性能的影响.
- 确定影响聚氨粘合剂膨胀比率和体积增加的关键组件.
主要方法:
- 自由膨胀试验测量密度和温度变化.
- 粒子群优化算法用于识别化学反应的动力参数.
- 数字模拟集成化学动力学和流体流动方程,以建模粘合剂膨胀.
主要成果:
- 膨胀比主要受到物理和化学泡剂度的影响,其次是异酸盐度.
- 聚醇度对膨胀比率的影响很小.
- 物理泡剂的溶解度决定了其最大度和对体积增加的贡献.
结论:
- 泡聚氨粘合剂的膨胀可以通过配方调整来控制.
- 优化泡剂和异酸盐度对于实现所需的膨胀性能至关重要.
- 材料溶解度是最大限度地扩展粘合剂的关键因素,用于特定的应用.
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