从混合循环碳化合物中制备非异酸聚氨:大豆油和CO2基聚乙烯碳酸盐)
Ga Ram Lee1, Eun Jong Lee1, Hye Sun Shin2
1HMC, Department of Nanotechnology and Advanced Materials Engineering, Sejong University, 209 Neungdong-ro, Seoul 05006, Republic of Korea.
Polymers
|April 27, 2024
概括
这项研究开发了可持续的非异酸聚氨 (NIPU),使用可再生循环碳化大豆油和一种新型的聚乙烯碳酸盐. 新的NIPU材料显示了更广泛的应用的热和机械性能.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 可持续化学 可持续化学
背景情况:
- 非异酸聚氨 (NIPU) 为传统聚氨提供了更安全的替代品.
- 从大豆油等可再生资源开发NIPU对于可持续性至关重要.
- 循环碳酸盐化学是NIPU合成的关键途径.
研究的目的:
- 合成和描述新的非异酸聚氨 (NIPU).
- 探索循环碳化大豆油 (CSBO) 和循环碳酸终结聚乙烯碳酸盐 (RCC) 的共聚合.
- 评估由此产生的NIPU的热和机械性能.
主要方法:
- 通过使用双金属化物催化剂共聚化二氧化碳和氧化物的方法合成聚乙烯碳酸) 聚.
- 聚乙烯碳酸) 聚与循环碳酸组的功能化,以产生RCC.
- CSBO和RCC与胺的共聚合形成NIPU.
主要成果:
- 当CSBO与RCC结合时,成功合成了固体NIPU.
- 来自CSBO和RCC的NIPU表现出良好的热稳定性.
- 与传统的基于CSBO的NIPU配方相比,观察到更好的机械性能.
- 仅使用RCC和胺的直接NIPU合成没有成功.
结论:
- 可再生CSBO和工程RCC的组合有效地创造了高性能NIPU.
- 利用可再生资源和碳捕获技术可以产生可持续的聚合物.
- 这些发现扩大了NIPU在各种行业的潜在应用.
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