在阿根廷Santa Rosa-Corrientes土壤中的粘土矿物质上吸附Ciprofloxacin
Nelly L Jorge1, María V Garrafa1, Jorge M Romero1
1Laboratorio de Investigaciones en Tecnología del Medio Ambiente, Área de Química Física, Facultad de Ciencias Exactas y Naturales y Agrimensura, Universidad del Nordeste, Corrientes 3400, Argentina.
Molecules (Basel, Switzerland)
|April 27, 2024
概括
土壤中的抗生素污染正在增加. 这项研究揭示了抗生素西普罗夫洛克萨与粘土矿物质结合的两种不同的方式,其中一种形式在土壤中保持强烈.
科学领域:
- 环境科学 环境科学
- 土壤科学 土壤科学
- 材料科学 材料科学 材料科学
背景情况:
- 由于强化农业和人类消费,土壤中抗生素的存在正在增加.
- 粘土矿物质对抗生素等有机污染物具有显著的吸附能力.
- 了解抗生素与矿物之间的相互作用对于追踪土壤污染物至关重要.
研究的目的:
- 为了研究普洛素在阿根廷圣罗莎土壤的粘土矿物质部分的吸附.
- 通过实验和计算方法,阐明在蒙特莫里隆尼特粘土中西普罗夫洛克萨的插入机制.
- 为了确定控制西普罗夫洛克萨吸附和脱吸的热力学参数.
主要方法:
- 实验性吸附-脱附等热体进行并使用各种等热体模型进行分析.
- 用原子模型计算来模拟蒙特莫里隆石中西普罗夫洛克萨辛的间歇作用.
- 基于温度依赖的平衡常数进行了热力学分析 (,,自由能量).
主要成果:
- 在粘土矿物质上发现了两种不同的吸行为.
- 观察到一种低吸收率的西普罗夫洛克萨,在实验中被消化.
- 发现,在土壤基质中,一种强度结合的西普罗洛克萨分数会持续存在.
结论:
- 齐普罗夫洛克萨在粘土矿物质上呈现双重吸附模式,影响其环境命运.
- 强烈的吸附成分表明,西普罗夫洛克萨在土壤中的长期持久性.
- 这项研究为土壤环境中的抗生素封存提供了关键的见解.
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