一种简单的方法,通过PVA/EVOH/MIDA制备离子交换膜,通过扩散透析进行酸回收
Hua Zhao1, Yueyue Zhang1, Yifei Gong1
1School of Materials & Chemical Engineering, Anhui Jianzhu University, Hefei 230022, China.
概括
使用PVA,EVOH和MIDA开发了新的离子交换膜 (AEM),用于废水处理. 这些交联膜在酸回收应用中表现出卓越的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 环境工程 环境工程
- 化学工程是化学工程的重要组成部分.
背景情况:
- 工业扩张导致严重的环境污染,需要有效的废水处理解决方案.
- 阳离子交换膜 (AEM) 对各种环境应用至关重要,包括废水处理和酸回收.
研究的目的:
- 使用聚乙烯醇 (PVA),乙烯-乙烯醇 (EVOH) 共聚合物和甲基氨基酸 (MIDA) 制备新型交联离子交换膜 (AEM).
- 为潜在的酸回收应用研究准备的AEM的结构性,综合性质和扩散透析性能.
主要方法:
- 溶剂造技术用于膜制备.
- 膜特征包括里埃变换红外光谱学,X射线光电子光谱学,扫描电子显微镜和传输电子显微镜.
- 评估的属性包括吸水,线性膨胀,离子交换能力,热,化学和机械稳定性,以及扩散透析性能.
主要成果:
- 交叉链接的AEM成功合成,形成了一个网络结构.
- 准备好的膜显示出出色的综合性质和扩散透析性能.
- 酸透析系数 (UH+) 范围从10.2到35.6×10−3 m/h,分离系数 (S) 范围从25到38,超过了商业的DF-120膜.
结论:
- 开发的交叉链接的AEM显示出了从工业废水中有效回收酸的巨大潜力.
- 增强的性能指标表明,这些膜是环境修复现有的商业选择的可行替代方案.
更多相关视频
相关概念视频
Dialysis
648
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
648
Ion Exchange
591
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
591
Detergent Purification of Membrane Proteins
5.2K
Detergents are used to purify the integral proteins of the membrane. The hydrophobic portion of the detergent can replace membrane phospholipids while solubilizing the membrane proteins. When detergent monomers reach a specific concentration in a solution called critical micelle concentration (CMC), they form micelles. Above CMC, the concentration of the detergent monomers remains in equilibrium with the micelle. The number of detergent monomers present in the CMC varies for each detergent, and...
5.2K
Potentiometry: Membrane Electrodes
567
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
567


