温室气体的捕获应用浸的二氧化与离子液体,深度环氧化溶剂和自然深度环氧化溶剂
Mariana Candia-Lomeli1,2, Beatriz Delgado-Cano3, Michelle Heitz2
1División de Ciencias Ambientales, Instituto Potosino de Investigación Científica y Tecnológica, Camino a La Presa San José 2055. Col. Lomas 4a. Sección, CP. 78216, San Luis Potosí, S.L.P, Mexico.
Environmental science and pollution research international
|April 29, 2024
概括
用离子液体 (ILs) 等溶剂浸多孔二氧化可增强温室气体 (GHG) 的捕获. 这种方法使用较少的溶剂有效减少二氧化碳 (CO2) 和氧化 (N2O).
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 温室气体 (GHG) 捕获对于减缓气候变化至关重要.
- 离子液体 (ILs),深层欧溶剂 (DES) 和天然深层欧溶剂 (NADES) 在温室气体减排方面表现有前景.
- 高溶剂粘度阻碍了传统吸收方法中的质量转移和气液接触.
研究的目的:
- 通过ILs,DES和NADES研究凝颗粒大小对CO2和N2O捕获的影响.
- 评估浸溶剂在多孔上对温室气体吸收的效率.
- 为了比较浸溶剂与散装溶剂在捕获温室气体方面的性能.
主要方法:
- 溶剂 (ILs,DES,NADES) 被浸在多孔的凝上.
- 热重力测量分析 (TGA) 确定了溶剂浸的程度.
- 福利埃变换红外光谱 (FTIR) 和X射线衍射 (XRD) 分析了表面的功能组和晶体结构.
- 一种静态头部空间方法测量了CO2和N2O分区系数.
主要成果:
- 凝上的溶剂浸度在36.8%至43.0% (重量/重量) 之间.
- 二氧化碳的分配系数从0.005到0.067不等,而N2O的分配系数从0.005到0.032.
- 与CO2相比,浸颗粒对N2O的亲和力更高.
- 浸颗粒只需要40%的散装溶剂来达到可比的温室气体捕获能力.
结论:
- 在凝上浸IL,DES和NADES有效地提高了GHG捕获效率.
- 这种方法克服了散装溶剂的粘度限制,改善了气液接触.
- 浸溶剂为减少二氧化碳和二氧化提供了一种更有效和潜在的成本效益高的方法.
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