凝的成分-防性能关系和相应的机制
Shichen Zhu1, Yan Jin2, Jiehang Yu2
1College of Food Science and Technology, Zhejiang University of Technology, Hangzhou, China; Zhejiang Key Laboratory of Green, Low-carbon and Efficient Development of Marine Fishery Resources, Hangzhou 310014, China; National R&D Branch Center for Pelagic Aquatic Products Processing (Hangzhou), Hangzhou, China; Collaborative Innovation Center of Seafood Deep Processing, Dalian Polytechnic University, Dalian 116034, China.
International journal of biological macromolecules
|April 30, 2024
概括
来自鱼的凝分离物表现出明显的抗性能. 一部分抑制冰核形成,另一部分有效阻止冰晶生长,为冷保护剂的开发提供了洞察力.
科学领域:
- 生物材料科学 生物材料科学
- 食品科学 食品科学 食品科学
- 生物物理学的生物物理.
背景情况:
- 凝具有固有的功能分数 (凝和冰相亲),使其成为潜在的冷保护剂.
- 了解凝成分和防性能之间的关系对于其应用至关重要.
研究的目的:
- 研究来自鱼的不同凝分数 (HW-PSG和LW-PSG) 的独特防性能.
- 阐明冰核抑制和冰再结晶抑制 (IRI) 的基本机制.
主要方法:
- 根据凝和结冰特性,从鱼中制成HW-PSG和LW-PSG的凝.
- 热歇斯底里斯 (THA) 测量以评估冰核形成.
- 冰再结晶抑制 (IRI) 试验和分子动力学模拟以研究防机制.
主要成果:
- LW-PSG 呈现出较高的热歇斯底里斯 (THA) 值,这表明抑制了冰核形成.
- 高温PSG表现出强大的冰再结晶抑制 (IRI) 能力,导致较小的冰晶 (210-550μm2).
- 分子动力学模拟显示,HW-PSG的密集微观结构限制了水分子的迁移,减缓了冰的生长,而LW-PSG则利用键和疏水相互作用来抑制核形成.
结论:
- 低温PSG有效抑制冰核形成,而高温PSG在抑制冰再结晶方面表现出色.
- 该研究阐明了凝分量的独特防机制,为通过组成调节增强基于凝的冷保护剂提供了基础.
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