对低地幔相稳定性的的影响
Elena-Marie Rogmann1, Eleanor S Jennings1,2,3, Jennifer Ross1
1School of Earth Sciences, University of Bristol, Bristol, BS8 1RJ UK.
概括
稳定了下层地幔中的相 (NAL和CF),影响了它们在玄武岩构成中容纳的能力. 这些发现澄清了极端压力下的相位关系.
科学领域:
- 矿物学和石矿学研究.
- 高压地质物理学 高压地质物理学
- 地质化学 地质化学
背景情况:
- 酸铁 (CF) 和新相 (NAL) 是下层地幔中中洋基岩 (MORB) 构成中过量的宿主.
- 简化系统中已知CF和NAL的稳定场,但在下层地幔条件下,额外的组件仍然不清楚.
研究的目的:
- 在较低地幔压力下研究含化合物中相相 (CF和NAL) 的相关系.
- 为了确定石 (KAlSiO4) 对CF和NAL的稳定性和溶性的影响.
主要方法:
- 在nepheline-kalsilite-spinel结合的nepheline顶部周围的一系列组成上进行的实验石器.
- 实验是在高压 (2878 GPa) 和恒温 (2000 K) 下进行的.
主要成果:
- 显著影响相位关系,稳定NAL至至少71GPa,压力远远超过其在无系统中的稳定性.
- CF的稳定场扩大,以增加压力并包含更多的,在68 GPa时显示出显著的溶解性.
- 证实CF和NAL在下层地幔条件下的MORB组合物中是适合的宿主.
结论:
- 在稳定NAL和扩大CF稳定场在下层地幔矿物质组合中起着至关重要的作用.
- 这些发现对理解地球下层地幔中和的地化学循环有意义.
- 预计K-荷兰石在地幔下层压力 (2848 GPa) 的沉积物组成中与CF和NAL一起稳定.
更多相关视频
05:50Facile Preparation of Ultrafine Aluminum Hydroxide Particles with or without Mesoporous MCM-41 in Ambient Environments
Published on: May 11, 2017
10.9K
11:50Metal-silicate Partitioning at High Pressure and Temperature: Experimental Methods and a Protocol to Suppress Highly Siderophile Element Inclusions
Published on: June 13, 2015
12.5K
相关概念视频
Alkali Metals
19.3K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.3K
Factors Affecting Solubility
33.4K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.4K
Ionic Strength: Effects on Chemical Equilibria
1.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.5K
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate
11.4K
Alkenes can be dihydroxylated using potassium permanganate. The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
11.4K
Qualitative Analysis
22.3K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
22.3K
Common Ion Effect
41.6K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Châtelier’s principle. Consider the dissolution of silver iodide:
41.6K
