压力变化通过形成由相反电荷的聚合物表面活性剂系统的凝聚形成的膜
Behnam Keshavarzi1,2, Georg Reising2, Mohsen Mahmoudvand3
1Helmholtz-Zentrum Dresden-Rossendorf, P.O. Box 510119, 01314 Dresden, Germany.
概括
通过桑坦和CTAB表面活性剂协形成囊,涉及膜生长和压力变化. 了解这些动态有助于开发适合各种应用的定制封装.
科学领域:
- 生物聚合物-表面活性剂相互作用
- 合体和接口科学科学
- 材料科学是一种材料科学.
背景情况:
- 通过克桑坦和CTAB表面活性剂的同化形成囊尚未完全理解.
- 膜形成和质量转移的动态过程需要详细的研究.
研究的目的:
- 阐明囊形成过程中质量转移和膜生长的机制.
- 描述聚合物-表面活性剂复合物的形成及其对囊性质的影响.
- 研究聚合物和表面活性剂参数对囊压力和膜结构的影响.
主要方法:
- 在溶液-空气界面测量表面张力和表面弹性.
- 焦显微镜以图像膜生长.
- 随着时间的推移监测囊压力.
主要成果:
- 在接口上的吸附行为与囊形成趋势相关.
- 膜交叉连接和收缩导致初始压力上升.
- 由于水的扩散和透,囊的收缩和压力下降.
结论:
- 凝聚力驱动的膜形成导致拉伸应力和压力增加.
- 透有助于囊收缩和压力下降.
- 洞察力使得量身定制的囊生产和改进的封装协议可用于工业应用.
相关概念视频
Colloids
17.5K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.5K
Membrane Fluidity
152.1K
Cell membranes are composed of phospholipids, proteins, and carbohydrates loosely attached to one another through chemical interactions. Molecules are generally able to move about in the plane of the membrane, giving the membrane its flexible nature called fluidity. Two other features of the membrane contribute to membrane fluidity: the chemical structure of the phospholipids and the presence of cholesterol in the membrane.
152.1K
Entropy and Solvation
7.0K
The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
7.0K
Solubility
17.5K
Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules,...
17.5K
Intermolecular Forces
58.2K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.2K
Mechanisms of Membrane Domain Formation
3.0K
Different physical properties of lipids and proteins allow them to localize and form distinct islands or domains in the membrane. Some membrane domains are formed due to protein-protein interactions, whereas others are formed due to the presence of specific lipids such as sphingolipids and sterols—for example, large proteins, such as bacteriorhodopsin, aggregate and create distinct domains.
Another mechanism for membrane domain formation involves membrane proteins interacting with...
Another mechanism for membrane domain formation involves membrane proteins interacting with...
3.0K


