通过基质介导的C-H激活和脱C-N合合成印度林,不需要过渡金属

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Updated: Jun 27, 2025

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

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Christian Weindl1,2, Lukas Hintermann1,2

  • 1School of Natural Science, Department Chemie, Technische Universität München, Lichtenbergstr. 4, Garching bei München, 85748, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)
|May 1, 2024
PubMed
概括

一种新的没有过渡金属的方法通过C-H和C-F键激活合成了印度林. 这种多米诺反应提供了一条直接的途径,从简单的前体中获得有价值的1,2-利林多林支架.

关键词:
基本催化作用的基础催化作用在 C−H 激活过程中.多米诺反应是一个多米诺反应.印度林斯 (Indolines) 是一种印度林斯.和伊米尼斯的伊米尼斯.

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