阶段过渡和发光性质的变化诱导不同的有机在一个维的双倍矿
Qing-Jie Zhou1, Peng Cao1, Zi-Ning Zhou1
1Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
Inorganic chemistry
|May 2, 2024
概括
合成了两种新的有机-无机杂交双矿. 一个呈现出具有高量子产量的明亮黄色发光,而另一个显示出弱蓝光,归因于结构差异.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 光物理学的光学物理学
背景情况:
- 双矿 (DPs) 由于自我捕捉刺激子而被调查发光.
- 有机-无机混合DPs通过阴阳选择提供可调节的特性.
研究的目的:
- 使用特定的有机酸合成和描述新的有机-无机混合DP.
- 研究影响这些DP的发光的结构-属性关系.
主要方法:
- 合成了两种新的双矿: [(CH3) 3NCH2CHCH2] 2KInCl6 (1) 和 [CH3CHOHCH2NH2] 2KInCl6 (2).
- 通过X射线衍射和光谱学进行结构分析.
- 光发光量产量 (PLQY) 的测量.
- 密度函数理论 (DFT) 的计算.
主要成果:
- 化合物1显示明亮黄色的排放>90%PLQY,而化合物2显示弱蓝色的排放0.98%PLQY.
- 化合物1在324/307K时经历可逆相变;化合物2没有.
- 在K离子协调 (Cl与Cl和O) 和[InCl6]3-八面体扭曲的差异与发光效率相关.
结论:
- 这些DP的发光特性受到阳离子选择和由此产生的晶体结构的强烈影响.
- 化合物1中较高的PLQY与更大的八面体扭曲和内部距离有关.
- 这些发现为设计高性能发光材料提供了洞察力.
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