通过调节氧气空位,Fe3+激活磁石矿持续发光
Zhan Du1, Huijun Shang1,2, Bo Wang3
1State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences (CAS), Beijing, China.
概括
研究人员开发了一种新的近红外 (NIR) 持久发光 (PersL) ,使用铁 (Fe3+) 激活的甲酸盐 (SrGa12O19). 增强氧气空位显著提高了其长时间持续的发光,用于先进的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 发光的光度是非常的低.
背景情况:
- 宽带近红外 (NIR) 光谱对于各种应用至关重要.
- 铁 (Fe3+) 离子是NIR的无毒激活剂.
研究的目的:
- 为了合成和表征Fe3+激活的SrGa12O19 (SGO) NIR.
- 研究氧气空缺对持久发光 (PersL) 的影响.
主要方法:
- 合成Fe3+兴奋的SGO和富含氧气空位的VO-SGO:Fe3+.
- 分析相位和发光特性.
- 光学带间隙评估.
主要成果:
- 在326nm激发后,SGO:Fe3+显示了宽带NIR发射 (700-1000nm,峰值在816nm).
- 增加的氧空度激活了Fe3+离子中的持久发光.
- VO-SGO:Fe3+表现出长时间的耐用性和高电荷储存能力.
结论:
- 氧气空缺是激活Fe3+兴奋剂SGO中的NIR PersL的关键.
- 这项工作为开发高效,无Cr3+的NIR PersL光剂奠定了基础.
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