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基于玉米粉的环保粘合剂的制备和表征,具有突出的抗水性,抗菌性
Minghui Hou1, HongLei2, Xiaojian Zhou1
1Yunnan Key Laboratory of Wood Adhesives and Glued Products, College of Material science and Chemistry Engineering, Southwest Forestry University, 650224 Kunming, China.
概括
这项研究开发了一种来自玉米粉的新型氧化粉-六胺-尿素 (OCSHU) 粘合剂. OCSHU粘合剂提供了更好的防水和防,使其成为可持续的木材粘合解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 绿色化学 绿色化学
背景情况:
- 粉粘合剂是可持续的,无甲的,生物降解的粘合剂.
- 传统的粉粘合剂具有较高的粘度和较差的防水/菌性能.
- 对于木材加工应用,需要改进的基于粉的粘合剂.
研究的目的:
- 开发一种基于粉的新型粘合剂,具有用于木材粘合的增强性能.
- 合成和表征一个氧化粉-六胺-尿素 (OCSHU) 粘合剂.
- 为了优化合成过程并评估粘合剂的性能.
主要方法:
- 玉米粉被氧化使用酸盐形成氧化粉 (OCS).
- OCS与六胺尿素 (HU) 反应,形成了OCSHU粘合剂.
- 氧化条件 (氧化剂度,时间,温度) 和HU含量得到了优化.
主要成果:
- 使用13%NaIO4在55°C下24小时进行最佳氧化,然后以40%HU进行反应.
- 该OCSHU粘合剂实现了高干切削强度 (1.84 MPa) 和耐水性 (1.50 MPa,24小时冷水).
- 开发的粘合剂表现出良好的储存稳定性和耐菌性.
结论:
- OCSHU粘合剂是一种有前途的绿色生物质木材粘合剂.
- 这种新型粘合剂克服了传统粉粘合剂的局限性.
- OCSHU粘合剂为木材应用提供了可持续和高性能的替代品.
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