从点源排放的半挥发性有机化合物的动态气体/粒子分离过程的建模:定量分析和影响评估
Fu-Jie Zhu1, Li-Fu Wang2, Long-Ze Qu2
1School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300401, China; International Joint Research Center for Persistent Toxic Substances (IJRC-PTS), State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China.
The Science of the total environment
|May 4, 2024
概括
本研究介绍了一种模型,用于预测排放地点附近的半挥发性有机化合物 (SVOC) 的气体/粒子分离. 该模型强调了排放特性和分区系数如何影响SVOC达到平衡的时间,这对于大气运输研究至关重要.
科学领域:
- 环境化学环境化学
- 大气科学 大气科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 污染点源对环境和人类健康产生重大影响.
- 要了解半挥发性有机化合物 (SVOC) 的大气分散,需要考虑气/粒子 (G/P) 分离动态.
研究的目的:
- 开发SVOCs动态G / P分区过程的预测模型,考虑排放影响.
- 分析影响气体和粒子阶段SVOCs时间依赖度的因素.
主要方法:
- 开发了一个模型来预测SVOCs的动态G/P分区.
- 研究了排放颗粒物比例 (φ0) 和八醇-空气分区系数 (K<0xE2><0x82><0x9A><0xE2><0x82><0x90>) 对分区动态的影响.
- 将模型预测与稳定状态模型进行比较,以验证准确性.
主要成果:
- 对于气体 (C<0xE2><0x82><0x9C>) 和颗粒 (C<0xE2><0x82><0x99>) 的动态G/P分离过程中,SVOC的相位显著不同.
- 达到稳定状态的特征时间 (t<0xE2><0x82><0x9C>) 随着K<0xE2><0x82><0x9A><0xE2><0x82><0x90>而变化,并受到φ0.0的影响.
- 一些SVOC的稳定状态可能需要100多个小时,影响当地大气分散.
结论:
- 动态G/P分区对于精确的SVOCs局部大气运输研究至关重要.
- 在动态分区模型中,必须考虑SVOCs在排放中的颗粒物比例 (φ0).
- 模型提供了对SVOCs的环境命运和在排放源附近的运输的洞察.
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