醇氧酸电解质的设计原则和路径
Noel J Leon1,2, Stefan Ilic2,3, Xiaowei Xie2,4,5
1Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.
The journal of physical chemistry letters
|May 6, 2024
概括
使用理论辅助设计合成了新的离子电池电解质. 研究人员发现,这些电解质中的阴离子协调会影响库伦比克效率,从而提高离子电池的性能.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 多价离子电池提供了有前途的储能解决方案.
- 离子电池 (CIB) 具有吸引力,因为它拥有丰富的资源,高能量密度和安全性.
- 有限的室温可逆涂层电解质存在,通常使用弱协调离子 (WCAs) 与氧化物.
研究的目的:
- 使用理论辅助设计开发新的离子电解盐.
- 为了合成和表征新的和现有的电解盐.
- 调查CIB中WCA结构和库伦比效率之间的关系.
主要方法:
- 四种电解盐的一合成:Ca[Al]tftb) 4 2 ,Ca[Al]hftb) 4 2 ,Ca[Al]hfip) 4 2 ,和Ca[TPFA] 2 .
- 分析WCA的结构共同点,重点是氧化物与氧化物的四坐标/中心.
- 考伦比效率的评估及其与离子协调倾向的相关性.
主要成果:
- 成功合成了两个新的和两个已知的电解质盐.
- 以氧化物为基础的WCAs作为关键组件的识别.
- 证明了库伦比克效率与离子协调程度的依赖.
结论:
- 理论辅助设计可以创建有效的离子电池电解质.
- 具有特定氧化物结构的弱协调性离子对于可逆涂层至关重要.
- 控制阴离子相互作用对于优化离子电池中的库伦比克效率至关重要.
相关概念视频
Strength and Heat of Hydration
229
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
229
Hydration of Cement
223
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
223
Qualitative Analysis
22.3K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
22.3K
Ionic Crystal Structures
14.3K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.3K
Ionic Compounds: Formulas and Nomenclature
66.9K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
66.9K
Ionic Strength: Effects on Chemical Equilibria
1.4K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.4K


