用于离子电池的基于甘油三酸盐的阻燃高温电解质
Xinsheng Wu1, Tong Liu2, Young-Geun Lee1
1Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States.
ACS applied materials & interfaces
|May 6, 2024
概括
使用三氨酸的新型阻燃电解质使稳定,高能耗的可充电电池能够在100°C下工作. 这一突破提高了要求高的工业应用的安全性和循环寿命.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 高温可充电电池 (>70°C) 对工业应用至关重要,但在安全性,循环寿命,能量密度和成本方面存在局限性.
- 现有的高温电池技术受到有限的电解质选择的阻碍.
研究的目的:
- 开发一种新型的阻燃电解质,用于在100°C时稳定的电池循环.
- 提高高温电池的安全性,循环寿命和能量密度.
主要方法:
- 将三氨酸纳入电解质系统.
- 测试金属半电池与基于三乙的电解质和各种阴极化学.
- 性能评估包括库伦比效率和循环寿命.
- 使用商业规模袋式电池的指甲穿透测试进行安全评估.
主要成果:
- 在100°C时实现稳定的电池循环,使用基于三氨酸的阻燃电解质.
- 金属半电池表现出高能量密度,高库伦比效率和良好的循环寿命.
- 指甲透测试显示,受抑制的热量产生和在受损的袋细胞中提供了很好的安全性.
结论:
- 基于triacetin的电解质为高温可充电电池提供了一个有前途的解决方案.
- 开发的电解质提高了电池的性能和安全性,解决了当前技术的关键局限性.
- 这一进步为要求高的行业中可靠的高温电池应用铺平了道路.
更多相关视频
11:04Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
13.0K
11:25Identification and Quantification of Decomposition Mechanisms in Lithium-Ion Batteries; Input to Heat Flow Simulation for Modeling Thermal Runaway
Published on: March 7, 2022
4.5K
相关概念视频
Batteries and Fuel Cells
27.3K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.3K
Flame Photometry: Lab
243
In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
243
Acid Halides to Alcohols: LiAlH4 Reduction
2.8K
Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
2.8K
Ionic Bonding and Electron Transfer
41.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.4K
