通过水凝固定铁/固体碳源增强的地下水脱化:对脱和基质释放性能的影响
Wenhao Yu1,2, Lecheng Liu1,2, Ni Yan1,2
1Key Lab of Marine Environmental Science and Ecology, Ministry of Education, College of Environmental Science and Engineering, Ocean University of China, Qingdao, 266100, P. R. China. yanni@ouc.edu.cn.
Environmental science. Processes & impacts
|May 7, 2024
概括
水凝中的聚基酸盐 (PHB) 通过增加多孔性和微生物腐蚀,增强从零价值铁 (ZVI) 中释放的溶解铁. PHB含量影响微生物群落和铁氧化,对地下水脱至关重要.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 微生物学 微生物学
背景情况:
- 零价值铁 (ZVI) 和碳来源的水凝封装延长了地下水中的基板寿命.
- 碳来源和ZVI对基板释放和脱的相互影响尚不清楚.
研究的目的:
- 调查聚基酸盐 (PHB) 对微米大小的ZVI (mZVI) 在水凝中的溶解铁释放的影响.
- 阐明PHB对脱机制和微生物群落结构的影响.
主要方法:
- 在不同的重量比率下合成封装mZVI和PHB的水凝.
- 对PHB消耗,mZVI活性部位暴露和溶解铁释放的分析.
- 微生物群体分析以确定PHB对脱的影响.
主要成果:
- PHB的消耗速度比mZVI更快,暴露了更多的mZVI活性位点,并增加了溶解铁的释放.
- PHB增强了mZVI的水凝多孔性和微生物腐蚀,进一步促进了铁的释放.
- 较高的PHB含量有利于异质型微生物和减少溶解铁的氧化;较低的PHB含量导致Fe (II) 氧化和更多的混合型微生物.
结论:
- PHB含量对溶解铁释放动力学和ZVI载水凝中的微生物群体结构产生了关键影响.
- 这项研究提供了控制地下水脱的理论基础,使用水凝固定营养素和ZVI.
- 研究结果支持这种技术在现场进行地下水整治的实际应用.
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