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Updated: Jun 26, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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催化三组分C(sp3) /C(sp2) -H激活,通过双重指导组战略激活

Fu-Cheng Hou1, Jia-Le Zhang1, Zi-Rui Wang1

  • 1The Key Laboratory of Functional Molecular Solids, Ministry of Education, School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241002, China. zhongyuanli@ahnu.edu.cn.

Chemical communications (Cambridge, England)
|May 8, 2024
PubMed
概括

这项研究引入了Rh催化三组分反应,用于合成8-基醇衍生物. 这种新的方法有效地实现了C-H激活,使用单个中双向组策略.

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All ortho–para directors, excluding halogens, are activating groups. These groups donate electrons to the ring, making the ring carbons electron-rich. Consequently, the reactivity of the aromatic ring towards electrophilic substitution increases. For instance, the nitration of anisole is about 10,000 times faster than the nitration of benzene. The electron-donating effect of the methoxy group in anisole activates the ortho and para positions on the ring and stabilizes the corresponding...
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