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相关概念视频

Phase Transitions: Melting and Freezing02:39

Phase Transitions: Melting and Freezing

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Heating a crystalline solid increases the average energy of its atoms, molecules, or ions, and the solid gets hotter. At some point, the added energy becomes large enough to partially overcome the forces holding the molecules or ions of the solid in their fixed positions, and the solid begins the process of transitioning to the liquid state or melting. At this point, the temperature of the solid stops rising, despite the continual input of heat, and it remains constant until all of the solid is...
12.4K
Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

2.8K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
2.8K
Phase Transitions: Sublimation and Deposition02:33

Phase Transitions: Sublimation and Deposition

17.1K
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
17.1K
Cryo-electron Microscopy01:28

Cryo-electron Microscopy

3.3K
Conventional electron microscopy (EM) involves dehydration, fixation, and staining of biological samples, which distorts the native state of biological molecules and results in several artifacts. Also, the high-energy electron beam damages the sample and makes it difficult to obtain high-resolution images. These issues can be addressed using cryo-EM, which uses frozen samples and gentler electron beams. The technique was developed by Jacques Dubochet, Joachim Frank, and Richard Henderson, for...
3.3K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.1K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.1K
Sublimation01:03

Sublimation

738
Sublimation is the direct transformation of a solid to a gaseous state. For instance, at standard pressure and room temperature, solid carbon dioxide sublimes to gaseous carbon dioxide. The phase diagram depicts the conditions required for sublimation. This process occurs at the solid-gas phase boundary and is not observed above the triple point of the substance. The reverse of sublimation is called deposition, where a gaseous substance condenses directly into a solid. Sublimation and...
738

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相关实验视频

Updated: Jun 26, 2025

A Microfluidic Approach for the Study of Ice and Clathrate Hydrate Crystallization
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一瞬间融化无形冰的冰.

Nathan J Mowry1, Constantin R Krüger1, Gabriele Bongiovanni1

  • 1Ecole Polytechnique Fédérale de Lausanne (EPFL), Laboratory of Molecular Nanodynamics, CH-1015 Lausanne, Switzerland.

The Journal of chemical physics
|May 9, 2024
PubMed
概括
此摘要是机器生成的。

研究人员发现,用激光快速化无形冰会使其结晶,即使在快速加热速度下. 这与实现玻璃化的快速冷却形成鲜明对比,为水提供了新的洞察力.

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科学领域:

  • 物理化学 物理化学
  • 材料科学 材料科学 材料科学
  • 生物物理学的生物物理.

背景情况:

  • 水可以通过快速冷却来玻璃化 (形成玻璃),避免在深度超冷状态的"无人之地"中结晶.
  • 了解水在这种超冷状态下的行为对于包括冷电子显微镜在内的各种科学领域至关重要.

研究的目的:

  • 为了研究反向玻璃化过程:使用微秒激光脉冲快速化无形冰.
  • 为了阐明极端加热条件下水的结晶机制.

主要方法:

  • 使用高功率微秒激光脉冲,对纯水样品 (无形冰) 进行闪融化.
  • 时间解析的电子衍射观察激光加热期间和之后的结构变化.
  • 无形固态水和超灭玻璃水之间的结晶动力学的比较.

主要成果:

  • 尽管加热速度极高 (>5 × 10^6 K/s),但观察到水的暂时结晶.
  • 这种结晶发生了即使类似的冷却速率 (10^7 K/s) 可以实现玻璃化.
  • 对于不同形式的无形冰,确定了不同的结晶动力学.

结论:

  • 这项研究揭示了无形冰在激光诱导的快速融化过程中出乎意料的结晶行为.
  • 这些发现挑战了关于水的相变的假设,并提供了关于其在"无人之地"的动态的新数据.
  • 这些结果对于推进微秒时间解析的冷电子显微镜技术至关重要.