白光发射Eu (III) 综合体通过连接体工程及其在近紫外线白光发射二极管和温度计冷却中的应用
Swetha Maredi1, Sibani Mund1, Sandhya Rani Nayak1
1Department of Chemistry, Indian Institute of Technology, Hyderabad, Kandi, Sangareddy-502285, Telangana, India.
概括
新型的imidazo-bipyridyl配体可以为固态照明 (SSL) 创建单元白光材料. 这些材料提供了出色的色彩染和潜在的先进的温度传感应用.
科学领域:
- 材料科学 材料科学 材料科学
- 摄影化学的使用.
- 有机化学 有机化学
背景情况:
- 固态照明 (SSL) 需要高质量的白光.
- 现有的白光发射材料往往涉及多个组件.
- 欧洲 (Eu) 复合体正在探索发光应用.
研究的目的:
- 设计新型的imidazo-bipyridyl配体用于Eu-复合体.
- 为了实现模仿阳光的多重排放,以提高白光质量.
- 研究这些复合物的潜力,作为单元白光发射材料.
主要方法:
- 合成具有纳基组的新型伊米达佐-双皮里迪尔配体.
- 配体和Eu复合体光发光的表征.
- 密度函数理论 (DFT) 计算用于能量转移分析.
- 白色发光二极管 (WLED) 的制造.
主要成果:
- 体表现出绿蓝色的辐射,将激发转移到可见光谱.
- 欧复合体表现出双重发射行为,产生白光.
- 观察到从连接体到Eu离子的能量转移不完全.
- 制造的WLED实现了高颜色染指数 (CRI ~93%).
- 综合体显示出温度传感和蒸发发光研究的潜力.
结论:
- 新型的imidazo-bipyridyl配体使得单组件白光发射Eu-复合物的产生成为可能.
- 这些综合体为SSL应用提供优越的白光质量.
- 开发的材料显示了超越照明的先进传感技术的前景.
相关概念视频
Photoluminescence: Applications
387
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
387
Photoluminescence: Fluorescence and Phosphorescence
2.0K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
2.0K
Colors and Magnetism
11.6K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.6K
Variables Affecting Phosphorescence and Fluorescence
498
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
498
Fluorescence and Phosphorescence: Instrumentation
589
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
589


