CO2气化对氧化燃料燃烧中的氧化氧化物排放的影响
Zilong Wang1, Anyao Jiao1, Feng Liu2
1School of Energy and Power Engineering, University of Shanghai for Science and Technology, Jun Gong Road 516, Shanghai 200093, China.
The journal of physical chemistry. A
|May 10, 2024
概括
通过促进碳反应,二氧化碳 (CO2) 气化有助于在氧燃料燃烧过程中减少氧化 (NO). 这一过程增强了NO的减少,特别是通过一氧化碳 (CO) 的产生.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 燃烧科学 燃烧科学
- 材料科学 材料科学 材料科学
背景情况:
- 氧化燃料的燃烧回收烟气,增加氧化 (NO) 度.
- 了解二氧化碳 (CO2) 气化机制对于NO减少策略至关重要.
研究的目的:
- 研究氧气燃料燃烧过程中在煤炭上二氧化碳气化的分子层次机制.
- 确定二氧化碳气化对NO减少途径的影响.
主要方法:
- 运用密度函数理论 (DFT) 和过渡状态理论 (TST).
- 采用了齐克萨克式碳和碳的模型来模拟二氧化碳吸附和气化反应.
- 分析了分子层面的反应途径,能量障碍和反应速率.
主要成果:
- 碳二氧化碳气化受益于齐格扎格的燃烧模式,降低能源障碍并增加反应速度.
- 在煤炭中存在气时,气化最初释放NO,收缩芳香环,并在高温下产生CO.
- 二氧化碳气化促进了均和异质的NO减排,主要是通过产生二氧化碳.
结论:
- 二氧化碳气化在氧化燃料燃烧过程中增强NO减少方面发挥着重要作用.
- 该过程加快了煤炭的消耗和NO的形成,间接有利于还原反应.
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