基于聚胺硫酸盐的水泥超级增塑剂的物理化学特性评估
Asta Judžentienė1, Agnė Zdaniauskienė1, Ilja Ignatjev1
1Department of Organic Chemistry, Center for Physical Sciences and Technology, Saulėtekio Avenue 3, 10257 Vilnius, Lithuania.
Materials (Basel, Switzerland)
|May 11, 2024
概括
超级塑化剂 (SPs) 对水泥在放射性废物处理中至关重要. 这项研究发现,聚胺硫酸盐 (PMS) 超塑性剂具有出色的热和化学稳定性,在性环境中确保长期安全.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 核工程 核工程是指核工程.
背景情况:
- 在放射性废物储存库中的工程障碍物中,水泥材料至关重要.
- 有机超塑剂 (SPs) 增强水泥性能,但可能会影响长期的安全性.
- 将SPs入地下水中可能会影响放射性核酸的迁移.
研究的目的:
- 为了评估聚胺硫酸盐 (PMS) 超可塑剂的化学和热稳定性.
- 评估PMS超级增塑剂对放射性废物处理安全性的潜在影响.
- 为了确定 PMS 在性水溶液中的降解率.
主要方法:
- 水泥的特性 (CEM I 42.5 R) 组成和表面积.
- 使用WD-XRF,拉曼光谱和热重力学分析分析PMS超塑剂的分析.
- 在3年内通过拉曼和UV/Vis光谱仪评估PMS在水溶液中的性降解.
主要成果:
- 超级可塑化剂PMS表现出高温稳定性,最高可达270°C.
- 在3年内,在高性溶液 (pH9.9-12.9) 中没有观察到PMS的显著降解.
- 在10天的时间里,水泥液显示pH值微不足道增加.
结论:
- 聚胺硫酸盐 (PMS) 超塑性剂在高度性条件下表现出极好的热和化学稳定性.
- 观察到的稳定性表明PMS适合用于用于放射性废物处理的水泥材料.
- 进一步的研究可能会证实存储库环境中的长期性能和安全影响.
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