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通过功能化石墨烯氧化物作为核化剂合成具有高结晶性和机械性能的聚乙烯二甲 (PET)

Yingdi Dan¹, Yao Wang¹, Miaorong Zhang¹

¹Institute of Hybrid Materials, National Center of International Research for Hybrid Materials Technology, National Base of International Science & Technology Cooperation, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China.

Molecules (Basel, Switzerland)

|May 11, 2024

概括

研究人员开发了一种新型功能化石墨烯氧化物核化剂 (GITP),以增强聚乙烯二甲 (PET) 结晶和机械性能. 这一创新显著提升了PET.

科学领域:

材料科学材料科学材料科学
聚合物科学聚合物科学
纳米技术纳米技术

背景情况:

聚乙烯二甲 (PET) 是一种广泛使用的聚,在结晶和机械性能方面存在局限性.
提高PET的性能对于扩大其在各种行业中的应用至关重要.
石墨烯氧化物 (GO) 已显示出作为强化剂的潜力,但需要功能化才能获得最佳的兼容性.

研究的目的:

合成一种新的功能化石墨烯氧化物核化剂 (GITP) 用于PET.
研究GITP对PET结晶行为和机械性能的影响.
建立一个有效的战略,使用功能化的GO来增强PET聚.

主要方法:

使用西兰合剂 (IPTES) 和聚合物块 (ITP) 合成GITP.
通过融混合来制备PET/GITP纳米复合材料.
描述PET和PET/GITP的热稳定性,结晶性质和抗拉强度.

主要成果:

与纯PET相比,PET/GITP纳米复合材料表现出增强的热稳定性和结晶性质.
化温度从244.1°C增加到257.1°C;结晶半衰期从595秒减少到201秒.
结晶温度从185.1°C增加到207.5°C,拉伸强度从50.69 MPa提高到66.8 MPa.

结论:

合成的GITP有效地作为PET的核化剂.
功能化的GO显著改善了PET的结晶和机械性能.
这项研究提出了一种可行的方法,可以使用功能化石墨烯氧化物增强PET聚.

关键词:

它具有结晶性质的特性.石墨烯氧化物石墨烯氧化物机械性质机械性质机械性质聚乙烯甲酸) 是一种聚乙烯甲酸.

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