聚乙烯薄膜通过酸接种进行表面修改
Ana Luisa Grafia1,2, Silvia Elena Barbosa1,2
1Planta Piloto de Ingeniería Química, PLAPIQUI (UNS-CONICET), Bahía Blanca 8000, Argentina.
Polymers
|May 11, 2024
概括
研究人员开发了一种新方法,使用酸 (BA) 移植修改聚乙烯 (PE) 薄膜表面. 这种表面修改增强PEPE.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
背景情况:
- 聚乙烯 (PE) 薄膜广泛使用,但具有疏水表面,限制它们对极性物质的粘附.
- 提高PE的表面极性对于需要增强表面相互作用的应用,如印刷和涂层,至关重要.
研究的目的:
- 开发一种有效的聚乙烯 (PE) 薄膜表面修饰方法.
- 通过化接种,增强PE薄膜对极性物质的表面亲和力.
- 评估使用改性PE薄膜用于包装和用水性油墨打印等应用的可行性.
主要方法:
- 使用化 (AlCl3) 和酸 (BA) 连续喷在热软化表面上的PE薄膜的表面修饰.
- 通过比较化学,形态和热分析来评估接种反应.
- 通过比较经过修改和未经修改的PE薄膜的水彩亲和力来评估表面性能变化.
主要成果:
- 证实了基酸 (BA) 在PE薄膜表面上的基化接种成功,仅限于表面层.
- 接种过程形成了基酸复合物,显著提高了表面对极性化合物的亲和力.
- 经过修改的PE薄膜对水彩增强了附着性,表明表面性能从疏水性转变为亲水性.
结论:
- 拟议的酸 (BA) 化接种方法有效地改变PE薄膜表面,增强其极性.
- 表面修改保留了PE薄膜的散装特性,同时使其适合使用水性油墨打印.
- 这种技术为需要可涂或可打印PE表面的应用提供了可行的解决方案,例如在包装行业.
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