通过薄膜中的有机扩散梯度 (o-DGT) 对土壤中硫黄胺生物可访问性的影响:基于微塑料聚合物,老化和土壤特性进行区分
Baochen Li1, Chunli Zhu1, Da Ouyang1
1Sino-Spain Joint Laboratory for Agricultural Environment Emerging Contaminants of Zhejiang Province, College of Environmental and Resource Sciences, Zhejiang Agriculture and Forestry University, Hangzhou 311300, China.
The Science of the total environment
|May 11, 2024
概括
微塑料 (MPs) 和抗生素如硫法 (SDZ) 在土壤中共存. 议员们改变了SDZ.
科学领域:
- 环境化学环境化学
- 土壤科学 土壤科学
- 生态毒理学 生态毒理学
背景情况:
- 微塑料 (MP) 和抗生素在农业土壤中并存,这是由于灌和施肥等共同来源.
- 不同的MP聚合物类型和衰老对抗生素生物可访问性的影响仍然不太清楚.
- 了解这些相互作用对于评估土壤和生态系统健康至关重要.
研究的目的:
- 调查各种微塑料类型和老化如何影响在米和盐水土壤中硫黄 (SDZ) 的分布和生物可访问性.
- 评估土壤特性在调解这些MP-抗生素相互作用中的作用.
- 评估生物体增加抗生素吸收的潜在风险.
主要方法:
- 使用有机化合物薄膜中的扩散梯度 (o-DGT) 来测量硫法 (SDZ) 的分布.
- 修改了四种MP聚合物类型 (PE,PP,PA,PET) 和老化版本 (aPE,aPP) 的土和盐土.
- 分析了SDZ分区系数,土壤溶液度和o-DGT可变分数的变化.
主要成果:
- 土壤类型显著影响了SDZ分区;盐土表现出更高的流动性和较低的降解.
- 微塑料对SDZ分区产生了不同的影响:PP在米土壤中减少了它,而PE,PP和老PE在盐土中增加了它.
- 在盐土中,MP降低了土壤溶液中的SDZ,但在o-DGT阶段增加了它,表明增强了补给;年龄较大的MP有更大的影响.
结论:
- 微塑料改变了土壤中硫黄 (SDZ) 的分布和生物可访问性,其影响因MP类型和土壤条件而异.
- 盐水环境特别脆弱,因为MP增强了SDZ对土壤溶液的补给,增加了生物体的潜在吸收.
- 陈旧的微塑料带来了更大的风险,突出了土壤中塑料污染的长期环境问题.
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