在Candelaria IOCG地区,由于变化的构造体制造成的对比的岩化学物质
1Department of Geology and Millennium Nucleus for Metal Tracing Along Subduction, FCFM, Universidad de Chile, Plaza Ercilla 803, Santiago, Chile. rromero@ing.uchile.cl.
Scientific reports
|May 11, 2024
概括
这项研究揭示了两个不同的岩石阶段形成了巨大的Candelaria氧化铁-铜-金 (IOCG) 沉积物. 早期的减少岩产生了氧化铁酸盐 (IOA) 矿化,而后来的氧化岩产生了富含铜的IOCG矿石.
科学领域:
- 经济地质学 地质学
- 地质化学 地质化学
- 石化学 石化学是一门学科.
背景情况:
- 氧化铁-铜-金 (IOCG) 矿床是铜和关键元素的重要来源.
- 安第斯类型的IOCG沉积物形成了延伸的大陆弧,在时间上与岩有关,但在空间上与岩无关.
- 形成IOCG矿床的过程及其与氧化铁酸盐 (IOA) 矿化之间的联系尚不清楚.
研究的目的:
- 为了确定IOCG沉积物形成的肥沃性指示的岩特征.
- 为了研究与坎德拉里亚IOCG沉积物相关的岩石的地化学演变.
- 了解岩和坎德拉利亚两种不同的矿化阶段之间的关系.
主要方法:
- U-Pb 侵入性岩石的地质年代学.
- 的微量元素地化学分析.
- 重建岩石的氧化还原状态,含水量和温度.
主要成果:
- 随着时间的推移,Candelaria地区发生了岩石中的显著地化学转变.
- 最早的岩石阶段 (128-125万年) 具有特定的 Eu/Eu*比率和氧化还原条件.
- 矿石形成阶段 (118-115万年前和111-108万年前) 显示出不同的岩条件:减少/氧化,高/低温度和不同的水含量.
结论:
- 坎德拉里亚IOCG矿床是通过两个不同的矿石形成事件形成的.
- 第一个事件涉及降低,高温,缺水的岩石,导致IOA型矿化.
- 第二个事件涉及氧化,低温,富含水的岩石,产生Cu和S丰富的矿物化,覆盖了早期的IOA.
相关概念视频
Qualitative Analysis
22.3K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
22.3K
Ionic Strength: Effects on Chemical Equilibria
1.4K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
1.4K
Ladder Diagrams: Complexation Equilibria
341
Ladder diagrams are useful for evaluating equilibria involving metal-ligand complexes. The vertical scale of the ladder diagram represents the concentration of unreacted or free ligand, pL. The horizontal lines on the scale depict the log of stepwise formation constants for metal-ligand complexes and indicate the dominant species in all the regions.
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...
341
Alkali Aggregate Reaction in Concrete
94
The alkali-aggregate reaction in concrete involves natural siliceous minerals in aggregates reacting with alkaline hydroxides derived from cement alkalis. This reaction forms an alkali-silica gel that absorbs water, swells, and increases in volume, which is confined by the surrounding cement paste, creating internal pressures that crack and disrupt the concrete. The extent of expansion and damage can be partly attributed to the alkali-silica reaction's osmotic hydraulic pressure and the...
94
Constant Volume Calorimetry
27.1K
Calorimeters are useful to determine the heat released or absorbed by a chemical reaction. Coffee cup calorimeters are designed to operate at constant (atmospheric) pressure and are convenient to measure heat flow (or enthalpy change) accompanying processes that occur in solution at constant pressure. A different type of calorimeter that operates at constant volume, colloquially known as a bomb calorimeter, is used to measure the energy produced by reactions that yield large amounts of heat and...
27.1K
Trends in Lattice Energy: Ion Size and Charge
23.9K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
23.9K


