在模型油/盐水界面上青酸盐的吸附:溶剂极性的影响
Wei Wang1, Fujun Sheng2, Guifang Ou3
1Sinopec Petroleum Engineering Corporation, Dongying, Shandong 257026, People's Republic of China.
ACS omega
|May 13, 2024
概括
这项研究表明,较高的溶剂极性会削弱青聚合,降低原油乳液的稳定性. 确定了关键的青度,影响了乳液形成和稳定性.
科学领域:
- 石油工程是石油工程中的一个.
- 合体和表面科学科学
- 物理化学 物理化学
背景情况:
- 重型石油开采增加了对青烯聚合对原油乳液稳定性的影响的关注.
- 了解青在油/盐水接口中的行为,对于增强石油回收和加工至关重要.
研究的目的:
- 研究溶剂极性对界面性质和乳液稳定性的影响.
- 为了确定稳定乳液形成的关键青度.
- 在不同的溶剂组合下分析青烯聚合和扩散.
主要方法:
- 动态光散射实验用于测量青聚合物的大小和扩散系数.
- 界面张力测量以确定平衡点的界面膨胀模块.
- 溶剂 (甲甲/n-decane) 混合比率和青度的系统变化.
主要成果:
- 确定了稳定乳液形成的关键青度,随着溶剂极性而增加.
- 青聚合物的大小增加,扩散系数在临界度以上下降.
- 增强的溶剂极性削弱了青烯的聚合,增加了扩散系数.
- 均衡界面膨胀模块随着溶剂极性增加而下降,表明界面膜较弱.
结论:
- 溶剂极性显著影响青烯聚合和原油乳液稳定性.
- 溶剂极性增加导致青烯聚合减少,接口膜较弱.
- 结果提供了关于在重油加工中管理乳液稳定性的见解.
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