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Updated: Jun 26, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
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Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts

Published on: August 7, 2018

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异构接口 MnO2/RuO2与丰富的氧气空缺,用于在酸性介质中增强氧气演变

Zhiming Guan1, Qian Chen1, Lin Liu1

  • 1School of Materials Science and Engineering Ocean University of China 1299 Sansha Road, Qingdao, 266000, P. R. China. dongbohua@ouc.edu.cn.

Nanoscale
|May 13, 2024
PubMed
概括

开发新的二氧化/二氧化 (MnO2/RuO2) 异构接口显著增强了绿色生产氧化演化反应 (OER) 电催化剂,在酸性条件下表现出优越的活性和稳定性.

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Radical Oxidation of Allylic and Benzylic Alcohols

Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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Interfacial Electrochemical Methods: Overview01:06

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