在不等价双矿Bi2FeMnO6薄膜中的巨大铁电光伏效应
Xudong Liu1, Jie Tu1, Yue-Wen Fang2,3
1Institute for Advanced Materials Technology, University of Science and Technology Beijing, Beijing 100083, China.
Journal of the American Chemical Society
|May 14, 2024
概括
研究人员使用不等价元素替代增强了Bi2FeMnO6膜中的铁电光伏效应. 这一战略显著提高了效率,为先进的光电子和光催化应用提供了潜力.
科学领域:
- 材料科学
- 固态物理
- 光电子产品
背景情况:
- 对铁电,铁磁和光伏性能进行了探索.
- 带隙工程可以通过定制的离子组合和安排来实现.
- 现有的增强铁电光伏效应的方法需要优化.
研究的目的:
- 开发一种协同策略,以诱导双矿薄膜中的化学应变和电荷补偿.
- 调查A位替代在Bi2FeMnO6对铁电光伏性能的影响.
- 了解应变,电荷平衡和缺陷修改的基本机制.
主要方法:
- 在Bi2FeMnO6表面薄膜中进行非等效元素替代 (A位点).
- 高分辨率的HAADF-STEM成像
- 基于同步射线的X射线衍射和吸收光谱.
- 密度函数理论 (DFT) 的计算.
主要成果:
- 从30.62μA/cm2获得了约135.67μA/cm2的铁电光伏效应.
- 由于铁电极化的增强,光伏效率提高了5倍以上.
- 证实了不等价离子在诱导化学应变 (+1.92和-1.04GPa) 和电荷平衡中的双重作用.
- 观察到氧气空隙密度降低并抑制 Jahn-Teller 扭曲,从而改善了电子轨道杂交,光学吸收和铁电极化.
结论:
- 不等效元件替代是一种有效的策略,用于增强双矿的铁电光伏效应.
- 拟议的方法为高性能薄膜设备提供了一条道路,厚度低于100nm.
- 这种方法有望通过缺陷控制在光催化和其他功能材料中的应用.
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