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Updated: Jun 26, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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通过替代来限制分子流动性:对1,10-dicyanobullvalene的一个案例研究

Bin-Bin Pei1, Hongjuan Yang2, Cai-Yue Gao1

  • 1Nanocluster Laboratory, Institute of Molecular Science, Shanxi University, Taiyuan, China.

Journal of computational chemistry
|May 14, 2024
PubMed
概括

1,10-迪亚诺布尔烯 (DCB) 具有有限的流动性,其异构体仅限于14个,通过单个循环相互转换. 这种分子旋转器的行为与相关化合物有很大不同.

关键词:
1,10-迪亚诺布尔烯牛牛牛牛牛牛牛牛在平衡的过程中,平衡.流动性的流动性.限制的限制限制的限制.

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Stability of Substituted Cyclohexanes

This lesson discusses the stability of substituted cyclohexanes with a focus on energies of various conformers and the effect of 1,3-diaxial interactions.
The two chair conformations of cyclohexanes undergo rapid interconversion at room temperature. Both forms have identical energies and stabilities, each comprising equal amounts of the equilibrium mixture. Replacing a hydrogen atom with a functional group makes the two conformations energetically non-equivalent.
For example, in...
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