在高极性0D混合/基矿中自捕获激素排放由抗兴奋剂触发
Bo Zhou1, Feier Fang1, Zexiang Liu2
1School of Electronics and Information Engineering, Shenzhen University, Shenzhen 518060, China.
Journal of the American Chemical Society
|May 14, 2024
概括
基于的新型矿具有双重排放. 使用Sb3+产生高效的黄色绿色和红色光,突出显示格子极性
科学领域:
- 材料科学
- 固态化学
- 光物理学
背景情况:
- 在金属化物中,单价是常见的.
- 具有极极性A位离子的矿未被充分探索.
研究的目的:
- 引入使用极性离子的新型OD混合矿.
- 调查Sb3+兴奋剂对光学特性的影响.
主要方法:
- 0D (NH4) ((OH3) 3-InCl6) 单晶的合成
- 用光发光谱分析辐射特性.
- 调查格子极性和Sb3+兴奋剂的作用.
主要成果:
- 实现有效的宽带黄色绿色 (550 nm) 和红色 (630 nm) 双重发射.
- 光发光量子收益率 (PLQY) 达到86%.
- 由于格子中的两极分化环境,Sb3+染导致了双重排放.
结论:
- 格子极性显著影响Sb3+化矿的自我捕获激子排放.
- 极性贡献高达25%的斯托克斯转移能量,补充了雅恩-泰勒变形.
- 含有Sb3+的矿提供可调节的宽带发射,而晶格极性是关键因素.
相关概念视频
Valence Bond Theory
8.5K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
8.5K
Hybridization of Atomic Orbitals I
47.0K
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
47.0K
Hybridization of Atomic Orbitals II
32.2K
sp3d and sp3d 2 Hybridization
32.2K
Colors and Magnetism
11.6K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.6K
π Electron Effects on Chemical Shift: Aromatic and Antiaromatic Compounds
1.2K
In aromatic compounds, such as benzene, the circulation of (4n + 2) π-electrons sets up a diamagnetic or diatropic ring current around the perimeter of the molecule. This current induces a magnetic field that opposes the external field inside the ring and reinforces it on the outside. The protons in benzene are deshielded and exhibit high chemical shifts in the range 6.5–8.5 ppm. The shielding effect at the center of the ring is evident in complex aromatic molecules, such as...
1.2K
Types of Semiconductors
588
Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
588


