完全不含甲的侧链使燃料电池离子交换膜在中等IEC上实现显著的微相分离
Shoutao Gong1,2, Anmin Liu1,2, Naeem Akhtar Qaisrani3
1State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China.
ACS applied materials & interfaces
|May 15, 2024
概括
研究人员开发了新的离子交换膜 (AEMs),使用无甲的高化侧链. 这些AEM显示了增强的微相分离,从而提高了氧化物导电性和燃料电池性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 离子交换膜 (AEM) 中的疏水性侧链对于离子运输至关重要.
- 现有的碳化合物和半化链提供有限的微相分离,阻碍性能.
研究的目的:
- 设计和合成具有无甲完全化侧链的聚 () 烯 (aryl piperidinium) AEM.
- 通过最大化的热力学不相容性来增强微相分离和离子运输.
主要方法:
- 合成具有不同侧链疏水性的多 (?? 烯) AEMs.
- 分子动力学模拟以研究离子水化.
- 对氧化物导电性和H2/O2燃料电池性能进行电化学测试.
主要成果:
- 无甲完全化侧链AEM (PAP-pF-1) 在80°C时实现了124.9mS cm-1的氧导电性.
- 与含有碳化合物 (PAP-CH-1) 和半化物 (PAP-sF-1) 侧链的膜相比,PAP-pF-1表现出更高的性能.
- PAP-pF-1膜的峰值功率密度为1651 mW cm−2和在H2/O2燃料电池中超过300小时的耐用性.
结论:
- 没有甲的高化侧链有效地增强了AEM中的微相分离.
- 这种设计策略导致离子导电性和燃料电池性能显著改善.
- 该研究为开发用于能源应用的先进AEM开辟了新的途径.
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