测量用联合和常规聚合物结合剂制成的电池阴极中的热散和热潜力,使用操作式热量计
Sun Woong Baek1, Charlene Z Salamat2, Rodrigo Elizalde-Segovia3
1Mechanical and Aerospace Engineering Department, Henry Samueli School of Engineering and Applied Science, University of California, Los Angeles, Los Angeles, California 90095, United States.
概括
这项研究研究了离子电池中的合聚合物结合剂,发现它们与传统结合剂相比减少了热量产生. 在低速率下,电子导电性是关键,而离子导电性在高速率下更重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 传统的聚乙烯化物 (PVDF) 结合剂在离子电池中很常见.
- 结合聚合物由于其导电性,具有作为高级结合剂的潜力.
研究的目的:
- 评估聚合物结合物的电子和离子导电性对离子电池性能的影响.
- 为了比较新型聚-3,4-二二氧) 结合剂与PVDF在LiNi0.8Co0.15Al0.05O2 (NCA) 阴极中的行为.
主要方法:
- 运行异热热量计,以测量热量产生.
- 在电池循环期间进行热电位测量.
- 同聚合物和共聚物合聚合物结合物的合成和表征.
主要成果:
- 与PVDF相比,合聚合物结合剂减少了朱尔加热.
- 在LiNi0.8Co0.15Al0.05O2 (NCA) 氧化潜力以下观察到结合剂兴奋剂签名.
- 同聚合物在低速率 (电子导电性主导) 显示出较低的散热率,而共聚物在高速率 (离子导电性重要性) 显示出更好的散热率.
结论:
- 结合聚合物结合剂可以通过管理热量来提高离子电池的效率.
- 结合剂中电子电导率与离子电导率的相对重要性取决于循环速率.
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