在水泥糊中的PPEGMA-PVPA共聚合物的合成和吸附-分散特性
Shenzhen Li1,2, Dongliang Zhou1,2, Xin Shu1,2
1State Key Laboratory of High Performance Civil Engineering Materials Nanjing 210008 China lishenzhen@cnjsjk.cn.
RSC advances
|May 16, 2024
概括
一种新型含酸盐的超级可塑剂,聚乙烯糖醇 (甲基烯酸) - 聚乙烯酸 (PPEGMA-PVPA) 被合成. 这种新材料显著增强了对水泥的吸附性,与传统超级增塑剂相比,提高了分散性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 建筑化学 建筑化学
背景情况:
- 超级增塑剂对于提高混凝土可加工性至关重要.
- 开发具有性能改进的新型超级可塑剂是一个正在进行的研究领域.
- 含酸盐的聚合物可能会对水泥材料产生更强的吸附.
研究的目的:
- 为了合成和表征一种新的超级可塑剂,PPEGMA-PVPA,用酸盐部分.
- 为了研究单体料比对共聚合物结构和酸盐密度的影响.
- 为了评估PPEGMA-PVPA在水泥糊上的吸附和分散性能.
主要方法:
- 用于PPEGMA-PVPA合成的溶液基聚合.
- 使用FT-IR,1H NMR和ICP-OES进行了表征.
- 通过微积分测试,TOC和泽塔潜力分析进行性能评估.
主要成果:
- 成功合成了具有不同酸盐密度的PPEGMA-PVPA共聚合物.
- 大约70%的乙烯基酸 (VPA) 单体被聚合.
- 与参考聚碳酸超塑性剂相比,PPEGMA-PVPA在水泥糊上的吸附能力提高了1.4倍.
结论:
- 合成的PPEGMA-PVPA具有出色的吸附和分散性能.
- 酸盐部分有助于增强与水泥颗粒的相互作用.
- 这种新型超级可塑化剂在提高混凝土性能方面表现有前途.
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