占主导地位的P3型固体溶液相位过渡使高稳定性O3型离子阴极成为可能
Hao Guo1, Chenglong Zhao2, Dong Zhou3
1China Institute of Atomic Energy, Beijing 102413, P. R. China.
ACS applied materials & interfaces
|May 16, 2024
概括
研究人员通过将P型特征引入O3型分层氧化物来增强离子电池阴极. 这一战略提高了循环稳定性和速率性能,这对于下一代储能至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 层状O3型氧化物是离子电池的关键阴极材料,由于其高容量和简单的合成.
- 挑战包括在高电压下不可逆转的结构转变,阻碍循环稳定性和速率性能.
研究的目的:
- 了解Na-ion层氧化物中的组成-结构-性质相互作用.
- 为了提高O3型阴极材料的稳定性和性能.
主要方法:
- 将P型特征引入O3型层结构中.
- 在循环过程中实现P3主导的固体溶液相位过渡.
- 调查可逆的O3-P3-P3'结构转变与最小的体积变化.
主要成果:
- 经过修改的Na0.75Ni0.25Cu0.10Fe0.05Mn0.15Ti0.45O2阴极实现了~113 mAh/g的特定容量.
- 证明了特殊的循环稳定性,在900个循环后保持超过70%的容量.
- 在O3-P3-P3'结构转变过程中,观察到最小的和渐进的体积变化.
结论:
- 成功地将P型特征集成到O3型层氧化物中,以提高Na-ion电池的性能.
- 这些发现为先进的Na-ion电池阴极的组成-结构-性质关系提供了关键的见解.
- 这种方法为开发稳定和高性能离子电池提供了一个有前途的战略.
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