离子电池的故障是由重力加速的
Yifan Hao1,2, Ke Li1,2, Songtong Zhang2
1State Key Laboratory of Metastable Materials Science and Technology, Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse, Yanshan University, Qinhuangdao 066004, Hebei, China.
引力导致离子电池 (LIB) 中电解质分布不均,导致温度变化和内部电阻增加. 这种衰老机制,特别是在电池顶部,突出了长期储能应用的关键安全问题.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (LIB) 对于现代储能至关重要,但由于复杂的故障机制,它们面临安全挑战.
- 了解电池老化对于提高高能量密度LIB的安全性和可靠性至关重要.
研究的目的:
- 为了研究LiNi0.5Co0.2Mn0.3O2基于石墨的18650个LIB的老化机制,在室温储存两年内.
- 确定重力诱导的电解质分布对电池性能和降解的作用.
主要方法:
- 在室温下储存2年的圆柱形18650LIBs.
- 监测电池内部的温度变化.
- 分析部分内部阻力变化.
- 储存后拆卸和检查电极材料.
主要成果:
- 引力导致电解质分布不均,导致电池顶部和底部之间的温度差异大约为0.89°C.
- 观察到与温度变化相关的部分内部电阻的增加.
- 在顶部电极发现了显著的物质损坏,表明局部降解.
结论:
- 引力驱动的电解质不足是LIBs的关键衰老因素,加剧了副作用和材料降解,特别是在电池的顶部.
- 这一发现为LIB安全提供了新的视角,特别是对于大规模的长期应用.
- 解决电解质分布问题对于提高高能量密度电池的安全性和寿命至关重要.
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