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动态共价键调节高性能离子电池的涂/剥离行为
Yafei Guo1, Chong Luo1,2, Mingfang Yang1
1Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China.
Angewandte Chemie (International ed. in English)
|May 17, 2024
概括
使用动态共价键的新型人工接口稳定水性电池中的阳极. 这种接口自适应体积变化,并在应力下变厚,防止树的生长,提高电池循环性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 基于的水性电池 (ZAB) 面临的挑战是由于涂层/脱落过程中的体积变化,导致树状石的生长和表面腐蚀.
- 传统的界面层难以适应这些体积波动,导致不受控制的树形成和进化.
研究的目的:
- 开发一个动态的人工接口来稳定ZAB中的阳极.
- 为了减轻的进化和限制树扩张,使用自适应和剪切加厚接口.
主要方法:
- 在阳极上开发基于聚氧 (PBSC) 的智能人工接口,在阳极上具有动态B-O共价键.
- 在不同电流密度下调查接口的自适应性和剪切加厚性.
- 使用PBSC修改的阳极组装和测试对称电池和袋式电池.
主要成果:
- PBSC接口在低电流速率下表现出形状自适应特性,适应体积变化并抵抗进化.
- 在高电流速率下,接口表现出剪切加厚效应,抑制了树的生长.
- 带有PBSC的对称电池保持了4500小时的稳定循环,一个袋式电池实现了超过170mAhg-1.1的特定容量.
结论:
- 在PBSC接口中的动态共价键提供了稳定阳极的整体策略.
- 这种智能接口工程方法提高了循环性能,并解决了ZAB的关键局限性.
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