测量错误和对微型近红外光谱仪预处理的影响:作为研究案例的甜杏和苦杏的分类
Jokin Ezenarro1, Jordi Riu1, Hawbeer Jamal Ahmed2
1Universitat Rovira i Virgili, Department of Analytical Chemistry and Organic Chemistry, Campus Sescelades, 43007, Tarragona, Catalonia, Spain.
Talanta
|May 18, 2024
概括
微型近红外 (NIR) 光谱仪器提供快速测量. 分析错误结构和优化预处理对于可靠的结果至关重要,使甜杏和苦杏的准确分类成为可能.
科学领域:
- 分析化学 分析化学
- 频谱学是一种光谱学.
- 化学测量 化学测量 化学测量
背景情况:
- 近红外 (NIR) 光谱已经从桌面转向便携式设备.
- 微型NIR仪器提供快速,低样本预处理测量.
- 仪器特定优化对于来自各种便携式NIR设备的可靠数据至关重要.
研究的目的:
- 为了研究小型NIR设备中的测量误差结构.
- 确定最佳的预处理技术,以提高模型性能.
- 应用这些方法来分类甜杏和苦杏.
主要方法:
- 测量误差共变率和相关性矩阵的计算和视觉检查.
- 应用错误分析来优化便携式NIR设备的预处理.
- 使用三个低成本的便携式NIR仪器 (SCiO,FlameNIR+,NeoSpectra微开发套件) 进行甜杏和苦杏的分类.
主要成果:
- 通过对所有设备的错误矩阵检查,确定了最佳的预处理策略.
- 用所有测试的仪器成功地将苦杏从甜杏分类出来.
- FlameNIR+ 设备实现了最高的分类准确率,达到 98%.
结论:
- 错误结构分析对于描述小型NIR仪器至关重要.
- 优化的预处理显著提高了便携式NIR光谱模型的可靠性.
- 这种方法为新兴便携式NIR技术的性能提供了宝贵的见解.
相关概念视频
Atomic Absorption Spectroscopy: Lab
342
For AAS measurements, samples must be introduced as clear solutions, often requiring extensive preliminary treatment to dissolve materials like soils, animal tissues, and minerals. Common methods for sample preparation include treatment with hot mineral acids, wet ashing, combustion in closed containers, high-temperature ashing, or fusion with reagents.
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing...
Solutions containing organic solvents, such as low-molecular-mass alcohols, esters, or ketones, enhance absorbances by increasing...
342
Atomic Absorption Spectroscopy: Interference
738
Interference leads to systematic error in atomic absorption (AA) measurements by enhancing or diminishing the analytical signal or the background. These interferences can be grouped into three main categories: spectral interference, chemical interference, and physical interference.
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
Spectral interference occurs when signals from other elements or molecules overlap with the analyte signal, falsely elevating or masking the analyte's absorbance. This interference can be corrected using Zeeman,...
738


