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Updated: Jun 26, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

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通过选择性有机超基,通过催化抗-碳质解质解,轻松获得有机

Jacob Culvyhouse1, Daniel K Unruh1, Hans Lischka1

  • 1Department of Chemistry & Biochemistry, Texas Tech University, Memorial Dr. & Boston, Lubbock, Texas, 79409, United States.

Angewandte Chemie (International ed. in English)
|May 19, 2024
PubMed
概括

这项研究引入了一种创新的方法,用于使用有机超基催化,避免金属和盐,创建-碳键. 该过程选择性地用功能化了芳香和异芳香化合物,产生了新的stibine衍生物.

关键词:
它们是反的.没有金属的催化剂.机体催化剂是有机催化剂.皮尼克托根结合 皮尼克托根结合超级基质催化剂 超级基质催化

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A significant aspect of hydroboration–oxidation is the regio- and stereochemical outcome of the reaction.
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α-Substituted ketones or aldehydes can be synthesized from enamines by the Stork enamine reaction, named after its pioneer Gilbert Stork. Enamines are useful synthetic intermediates where the lone pair on nitrogen is in conjugation with the C=C bond. They resemble enolate ions, as the resonance forms of both species have a nucleophilic α carbon.
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In organic synthesis, the formation of products can be altered by changing the reaction conditions. For example, a dibromo addition product is formed when propene is treated with bromine at room temperature. In contrast, propene undergoes allylic substitution in non-polar solvents at high temperatures to give 3-bromopropene. In order to avoid the addition reaction, the bromine concentration must be kept as low as possible throughout the reaction. This can be achieved using N-bromosuccinimide...
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