材料进化的前景 由离子电池中阴侧反射充电引起的
Huang K David1, Po-Tuan Chen1, Wei-Mon Yan2,3
1Department of Vehicle Engineering, National Taipei University of Technology, Taipei 10608, Taiwan.
Heliyon
|May 20, 2024
概括
一种新的正弦充电方法可以比传统的CC-CV充电更好地保护离子电池石墨电极. 这种方法尽量减少对电极材料的损坏,提高电池的寿命和安全性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池是重要的能源,但它们的寿命和安全性取决于循环过程中的电极材料完整性.
- 了解循环寿命损坏机制对于提高电池性能和可靠性至关重要.
研究的目的:
- 研究不同充电方法对离子电池电极材料的影响.
- 为了比较使用传统和新型充电技术的阴极和阳极材料所遭受的损伤.
主要方法:
- 采用恒流-正弦反射充电 (CC-正弦) 方法,并将其与恒流-恒电压 (CC-CV) 进行比较.
- 商业充电的氧化 (LiCoO2) 阴极和石墨阳极电极超过100,300和500个周期.
- 使用EIS,SEM,XRD和拉曼光谱仪来分析电极材料降解.
主要成果:
- 在500个循环后,LiCoO2阴极结构保持稳定,无论充电方法如何.
- CC-CV方法对石墨阳极造成了重大损坏,形成了固体电解质接口 (SEI) 膜.
- 通过CC-Sinusoidal方法,可以使石墨电极材料保持在一个优异的状态.
结论:
- 与CC-CV相比,CC-Sinusoidal充电方法在保持石墨阳极完整性方面具有显著的优势.
- 这种新的充电方法对延长离子电池的循环寿命和提高离子电池的安全性有希望.
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