在/环氧树脂接口上凝结水对固化反应的影响
Satoru Yamamoto1, Yuta Tsuji2, Riichi Kuwahara3
1Center for Polymer Interface and Molecular Adhesion Science, Kyushu University, Fukuoka 819-0395, Japan.
Langmuir : the ACS journal of surfaces and colloids
|May 20, 2024
概括
表面上的水通过促进扩散和相互作用来加速环氧胺固化反应. 这种湿度效应在固化后仍然存在,影响轻量级移动应用中的粘合剂粘合.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 计算化学计算化学
背景情况:
- 环氧粘合剂对于轻量级的移动性组件至关重要.
- 表面很容易吸附水,影响粘合性能.
- 了解水在环氧胺相互作用中的作用至关重要.
研究的目的:
- 为了研究水聚合状态及其对环氧胺固化对烯酸的影响.
- 分析水对反应动力学和界面相互作用的影响.
- 为了阐明水分在环氧树脂应用中的作用.
主要方法:
- 分子动力学模拟的模拟.
- 密度函数理论计算密度函数理论计算
- 在固化前后对界面相互作用的分析.
主要成果:
- 水强烈吸附于,形成聚合物并扩散到环氧混合物中.
- 水在表面附近加速扩散和反应动力学.
- 接口相互作用在固化后发生变化,功能组与表面之间的结合发生变化.
结论:
- 水显著影响环氧胺固化动力学和的界面性质.
- 水的存在增强了粘合相互作用,特别是在最初的阶段.
- 结果提供了关于湿度对环氧树脂应用和粘附的影响的见解.
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