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Updated: Jun 25, 2025

Ammonia Synthesis at Low Pressure
Published on: August 23, 2017
固态立方氨在环境温度下在大气压力下的玻璃物质中稳定
Masao Morishita1, Hayate Miyoshi2, Haruto Kawasaki2
1National Institute of Materials Science (NIMS) (Formerly Department of Chemical Engineering and Materials Science), University of Hyogo Japan MORISHITA.Masao@nims.go.jp.
研究人员使用玻尿酸玻璃矩阵在室温下稳定了固体立方氨. 氨水晶 (NH3) 稳定性的这一突破为储存和行星科学研究开辟了新的可能性.
科学领域:
- 材料科学 材料科学 材料科学
- 行星科学 行星科学
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 氨 (NH3) 是一种对行星科学和储存有重大影响的化合物.
- 氨的低温立方晶相 (NH3 ......cr)) 在室温下不稳定.
- 气态氨 (NH3 ((g)) 对健康构成危害,需要安全的储存解决方案.
研究的目的:
- 第一次在室温下稳定固体立方氨 (NH3 ) .
- 探索氨在环境条件下作为储存介质的潜力.
主要方法:
- 在玻璃基质玻尿酸中封闭氨.
- 在大气压下合成和稳定立方水晶氨 (NH3 (((cr)) .
- 用热力学模拟来确认稳定,并评估准平衡状态.
主要成果:
- 在室温下成功合成和稳定立方水晶氨 (NH3 (((cr)) .
- 稳定NH3 (((cr) 的表征,其晶格常数为0.5165nm.
- 热力学模拟证实了稳定氨的准平衡状态.
结论:
- 在环境条件下稳定氨的低温阶段是可以实现的.
- 玻尿酸玻璃矩阵成功地限制和稳定了立方氨.
- 需要进一步的研究来开发用于将氨分解为和的催化矩阵.
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