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Updated: Jun 25, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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Published on: May 21, 2019

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通过基启用氧化添加形成的催化相关器官铜 (III) 复合物

Wenhao Yan1, Andrew T Poore2, Lingfeng Yin1

  • 1Department of Chemistry, University of Cincinnati, Cincinnati, Ohio 45221, United States.

Journal of the American Chemical Society
|May 21, 2024
PubMed
概括

这项研究揭示了铜I) 使用基形成铜III) 复合物的新途径,使得这些难以捉摸的催化中间体的详细研究成为可能.

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Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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Radicals adjacent to electron-donating groups are called nucleophilic radicals. These radicals readily react with electrophilic alkenes. The SOMO–LUMO interactions are the driving force for the reaction, where the high-energy SOMO of the electron-rich, nucleophilic radicals interacts with the low-energy LUMO of the electron-deficient, electrophilic alkenes. Such SOMO–LUMO interactions are the basis of reactive radical traps, affecting the selectivity in radical reactions. For...
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