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Updated: Jun 25, 2025

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
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Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

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三铜μ-Oxo/Hydroxo/Aqua复合体中的质子合电子转移的热力学

Saikat Mondal1, Weiyao Zhang1, Shiyu Zhang1

  • 1Department of Chemistry & Biochemistry, The Ohio State University, 100 West 18th Avenue, Columbus, Ohio 43210, United States.

Journal of the American Chemical Society
|May 21, 2024
PubMed
概括

这项研究揭示了多铜氧化酶 (MCO) 如何在三铜位点使用质子合电子转移 (PCET) 有效地减少氧气. 了解这些热力学解释了MCOs

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During the electron transport chain, electrons from NADH and FADH2 are first transferred to complexes I and II, respectively. These two complexes then transfer the electrons to ubiquinol, which carries them further to complex III. Complex III passes the electrons across the intermembrane space to Cyt c, which carries them further to complex IV. Complex IV donates electrons to oxygen and reduces it to water. As electrons pass through complexes I, III, and IV, the energy released aids the pumping...
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