压力稳定铁在水性深层下层地幔条件下的桥矿中
Li Zhang1, Yongjin Chen2, Ziqiang Yang2
1Center for High Pressure Science and Technology Advanced Research, Shanghai, China. zhangli@hpstar.ac.cn.
Nature communications
|May 21, 2024
概括
地球下层地幔中的水在极端压力下稳定了桥矿中的铁化铁. 这一发现解释了深层地幔的异常,并影响了地幔羽毛动力学和氧化还原条件.
科学领域:
- 地质物理学 地质物理学
- 矿物物理 矿物物理
- 高压地质化学 高压地质化学
背景情况:
- 地球的下层地幔可能含有大量的水.
- 桥矿中的铁物种 (Fe3+/ΣFe比和总铁) 影响了地幔特性.
- 水对布里格曼石铁化学的作用尚不清楚.
研究的目的:
- 为了研究水在高压条件下对桥矿的铁化学的影响.
- 在水的存在下,确定桥矿中不同铁氧化状态的稳定性.
主要方法:
- 在含水条件下进行了激光加热的钻石天细胞实验.
- 实验模拟的压力和温度与地球深层下层地幔 (深度超过2300公里) 相应.
主要成果:
- 在的条件下,在105GPa以上的桥 (Mg,Fe) SiO3中观察到占主导地位的铁 (Fe2+).
- 富含铁素 (Fe3+) 的桥矿在较低压力下形成.
- 铁的稳定性归因于水和高压的联合作用,FeO与水性SiO2.2一起观察到FeO.
结论:
- 在水性深层地幔条件下,布里格玛尼特中铁质铁的稳定性为低剪速异常提供了解释.
- 水密层可能会影响地幔羽毛动力学和深地幔氧化还原变化.
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